Dezincification Resistance of Copper Alloys with Zinc

The ISO 6509 Test,
Explained Properly

24 hours in hot copper chloride decides whether a brass may call itself DZR. What the test does, what the depth numbers mean, and what passing does — and does not — entitle anyone to claim.

1% CuCl₂ · 75°C · 24 h CW602N & CW724R Pass Material Property — Not an Approval
01
The Short Answer
The test in one paragraph
02
What Dezincification Is
And why it ruins brass from inside
03
The Test, Step by Step
Method per ISO 6509-1
04
Alloys: Pass or Fail
CW602N, CW724R vs CW614N, CW617N
05
The Honest Boundary
Test result ≠ product approval
06
FAQ
7 common questions answered
Section 01

The short answer

ISO 6509 is the accelerated laboratory test that determines whether a brass resists dezincification.

The Test in One Paragraph

Hot copper chloride, then a microscope

A prepared specimen is exposed to a 1% copper(II) chloride solution (12.7 g/L CuCl₂·2H₂O) at 75°C for 24 hours; it is then cut, polished and examined under an optical microscope, and the depth of the dezincified layer is measured in micrometres.

Part 1 defines the method; Part 2 covers assessment. A low measured depth is what earns alloys such as CW602N and CW724R the label DZR — dezincification resistant.

Test Parameters

At a glance

Solution1% CuCl₂ (12.7 g/L dihydrate)
Temperature75°C
Duration24 hours
Measurementdepth in µm, optical microscopy
Method / criteriaPart 1 / Part 2
Section 02

What dezincification does to brass

Brass is a copper–zinc alloy. In unfavourable water — soft, chloride-rich, warm or stagnant — the zinc can be selectively leached out of the structure. What remains looks like brass on the outside and behaves like sponge on the inside.

Cross-section
Sound brass uniform α/β structure — full strength After dezincification depth, µm porous copper-rich plug — colour changes, strength is gone The ISO 6509 verdict is exactly this depth, measured on a microsection after 24 h of accelerated attack.
Field failures rarely announce themselves: the part weeps at a thread, or a fitting shears at a wall that had quietly lost its zinc. The full failure-mode picture — including meringue dezincification under deposits — is covered in our brass corrosion guide.
Section 03

The test, step by step

Method per ISO 6509-1
1
Prepare — specimen cut, embedded, surface metallographically polished.
2
Expose — 1% CuCl₂ solution (12.7 g/L CuCl₂·2H₂O), 75°C, 24 hours.
3
Section — cross-section through the attacked face, ground and polished.
4
Measure — optical microscope; dezincification depth recorded in µm.
Where the pass mark comes from: the test yields a depth, not a verdict. The threshold is set by ISO 6509-2, the product standard or the certification scheme invoking the test — which is why the same measured depth can pass one specification and fail another. The commonly applied practical criterion for arsenical DZR brass is a maximum depth of 200 µm.
Why Accelerated?

A decade of soft water in a single day

Hot copper chloride drives the same selective zinc attack that aggressive service water produces over years. It ranks alloys by the mechanism that actually kills fittings — not by a proxy.

That is why DZR mandates in Australia, the Netherlands and Scandinavia are written around this test, and why serious water-fitting specifications cite it by number.

Section 04

Which brasses pass — and why

AlloyZn contentDZR mechanismTypical ISO 6509 outcomeUse where
CW602N · CuZn36Pb2As~36%Arsenic inhibitionResistant — ≤ 200 µm criterionDZR water-contact components, soft-water markets
CW724R · CuZn21Si3P~21%Silicon kappa-phase, intrinsicResistant — typically ≤ 100 µmLead-free + DZR programmes
C69300 · CuZn21Si3P~21%Silicon kappa-phase, intrinsicResistant — typically ≤ 100 µmUS lead-free programmes (NSF/ANSI 372 lead criterion)
CW614N · CuZn39Pb3~39%NoneNot resistant — fails in aggressive waterGeneral machining; neutral hard water
CW617N · CuZn40Pb2~40%NoneNot resistant — fails in aggressive waterHot forging + machining; neutral hard water
Typical Maximum Depth by Alloy (µm)
CW602N (arsenical) ≤ 200 µm criterion CW724R (silicon) typically ≤ 100 µm C69300 (silicon) typically ≤ 100 µm CW614N / CW617N not resistant — fails in aggressive water Lower is better. Pass thresholds are set by ISO 6509-2 or the certification scheme applying the test; values shown reflect our corrosion guide.
Where DZR is mandated or prudent: soft or low-mineral supplies, elevated chlorides, warm stagnant lines — and markets such as Australia, the Netherlands and parts of Scandinavia that require DZR grades for water fittings. In neutral hard water, standard CW614N/CW617N remain the faster-machining, lower-cost choice. Grade-selection help: alloy guide.
Section 05

A passed test is a material property — not an approval

The Honest Boundary

Two levels, two owners

Material level (this page): CW602N resists dezincification per ISO 6509; CW724R/C69300 meet the lead-content criterion referenced by NSF/ANSI 372. Both are properties of the alloy, evidenced per batch by an EN 10204 3.1 certificate.
Product level (the buyer's): WRAS, KIWA, DVGW, ACS and national positive lists approve the finished fitting or appliance — held by whoever places it on the market.

Brassland machines components — not finished valves — and does not cast. Material-level ISO 6509 evidence is agreed at ordering where a programme requires it.

DZR Parts, Machined to Drawing

CW602N and lead-free CW724R — cut to ±0.005 mm

CNC to Ø 150 mm, Swiss-type to ±0.005 mm (Ø 2–32 mm) — with the batch analysis on every shipment's 3.1 certificate documenting the alloy.

Request a Quote Corrosion Guide
Section 06

Frequently asked questions

What is the ISO 6509 test?
ISO 6509 is the standard accelerated laboratory test for the dezincification resistance of brass. A polished cross-section specimen is exposed to a 1% copper(II) chloride solution at 75°C for 24 hours, then sectioned and examined under an optical microscope, and the depth of dezincification is measured in micrometres. ISO 6509-1 defines the test method; ISO 6509-2 covers the assessment criteria.
What is a passing result in the ISO 6509 test?
The test itself measures a depth; the pass threshold comes from ISO 6509-2, the product specification or the certification scheme applying it. In common practice for arsenical DZR brass such as CW602N, a maximum dezincification depth of 200 μm is the widely applied criterion, and silicon brasses such as CW724R typically show 100 μm or less. The applicable scheme or customer specification always governs.
Which brass alloys pass the ISO 6509 dezincification test?
Arsenic-inhibited CW602N (CuZn36Pb2As) and the silicon brasses CW724R and C69300 (CuZn21Si3P) are dezincification-resistant and pass the test. Standard free-machining and forging brasses — CW614N (CuZn39Pb3) and CW617N (CuZn40Pb2) — are not dezincification-resistant and fail in aggressive water conditions.
Does passing ISO 6509 mean a part is approved for drinking water?
No. ISO 6509 characterises a material property — resistance to dezincification. Drinking-water approval (WRAS, KIWA, DVGW, ACS or national positive lists) applies to the finished product and is held by whoever places that product on the market. A component supplier provides DZR material with an EN 10204 3.1 batch certificate as the evidence base; the end-product approval is the buyer's.
When should I specify DZR brass instead of standard brass?
Specify DZR (CW602N or a silicon brass) where the part sees water with dezincification risk: soft or low-mineral water, elevated chloride content, warm stagnant conditions, or markets that mandate DZR such as Australia, the Netherlands and parts of Scandinavia. In neutral hard water, standard CW614N and CW617N perform well and machine faster.
What does dezincification actually do to brass?
It selectively leaches zinc out of the alloy, leaving a porous, copper-rich but mechanically weak layer. Externally the part can look intact apart from reddish patches; internally the affected depth has lost its strength, which is why failures appear as leaks or sudden breakage at threads and thin walls.
Can Brassland supply parts with ISO 6509 test evidence?
Brassland machines DZR brass CW602N and lead-free silicon brass CW724R/C69300 to drawing, and every shipment carries an EN 10204 3.1 certificate with the batch analysis that documents the alloy. Where a customer programme requires ISO 6509 test reports for the material, this is agreed at the ordering stage together with the material supply chain.
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Sources & scope. Test method per ISO 6509-1:2014 (Corrosion of metals and alloys — Determination of dezincification resistance of copper alloys with zinc — Part 1: Test method) and assessment per ISO 6509-2:2017, cross-checked against independent laboratory descriptions and Brassland's corrosion engineering guide. Provided as an engineering reference; the current official editions and the certification scheme applying the test govern.
Reference Library

Standard-by-standard deep dives

Dedicated reference pages with full value tables, diagrams and honest limits — one standard per page.

01
EN 10204 Certificates
2.1 · 2.2 · 3.1 · 3.2 — who signs what
02
ISO 2768 General Tolerances
Full f/m/c/v + H/K/L value tables
03
EN 12164 Machining Rod
The standard behind every turned part
04
ISO 6509 DZR Test
1% CuCl₂ · 75°C · 24 h — explained
05
EN 12165 Forging Stock
Stock → forge → EN 12420 → machining